Sumanene-functionalised bis(terpyridine)–ruthenium(<scp>ii</scp>) complexes showing photoinduced structural change and cation sensing
Junyi Han, Yumi Yakiyama, Youhei Takeda, Hidehiro Sakurai
Abstract
Ru( ii ) complexes with sumanene-functionalised terpyridine ligands exhibited dual emission via the TICT mechanism due to the relatively easy rotation around the sumanene–terpyridine bond axis. They also showed selective Li + sensing ability.
Topics & Concepts
TerpyridineRutheniumChemistryPhotochemistryPolymer chemistryStereochemistryCatalysisMetalOrganic chemistryPorphyrin and Phthalocyanine ChemistryMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials