Visible-light-induced selective hydrolipocyclization and silylation of alkenes: access to ring-fused quinazolin-4(3<i>H</i>)-ones and their silicon-substituted derivatives
Shoucai Wang, Ziren Chen, Fei Xue, Yonghong Zhang, Bin Wang, Shaofeng Wu, Yu Xia, Zhao Xiuli, Guangbin Jiang, Fanghua Ji, Chenjiang Liu
Abstract
A visible-light-induced intermolecular silylation and hydrolipocyclization using hydrosilane as the hydrogen and silicon source has been developed, which provided an efficient pathway for the synthesis of organosilanes and polycyclic quinazolinones.
Topics & Concepts
SilylationChemistrySiliconRing (chemistry)Intermolecular forcePhotochemistryCombinatorial chemistryOrganic chemistryCatalysisMoleculeRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques