Metal-cyanido molecular modulators of the sensing range and performance in lanthanide-based luminescent thermometers
Maciej Wyczesany, Jakub J. Zakrzewski, Barbara Sieklucka, Szymon Chorąży
Abstract
Ratiometric optical thermometry based on emission intensities and lifetimes of Eu( iii ) and Tb( iii ) centers is efficiently modulated by tetracyanidometallate linkers governing critical vibrational modes of the heterometallic d–f crystalline materials.
Topics & Concepts
LanthanideMaterials scienceLuminescenceMetal-organic frameworkMetalRange (aeronautics)Luminescent MeasurementsPhysical chemistryNanotechnologyOptoelectronicsChemistryOrganic chemistryIonMetallurgyComposite materialAdsorptionLuminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesAtomic and Subatomic Physics Research