Coordinated water molecule-induced solid-state superprotonic conduction by a highly scalable and pH-stable coordination polymer (CP)
Rupam Sahoo, Shaozhen Luo, Naresh Kumar Pendyala, Santanu Chand, Zhihua Fu, Madhab C. Das
Abstract
A highly scalable and pH-stable (2–10) Cu( ii )-bpy chain-based coordination polymer, IITKGP-101, is reported, where the SBUs are coordinated with ample water molecules acting as proton sources, thus leading to superprotonic conductivity.
Topics & Concepts
SBusPolymerMoleculeConductivityProtonMaterials scienceCoordination polymerThermal conductionSolid-statePolymer chemistryChemical engineeringCrystallographyChemistryMetal-organic frameworkPhysical chemistryOrganic chemistryPhysicsComposite materialAdsorptionQuantum mechanicsEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsOrganic and Molecular Conductors ResearchFuel Cells and Related Materials