Characterization and reactivity study of non-heme high-valent iron–hydroxo complexes
Kritika Keshari, M. Bera, Lucía Velasco, Sandip Munshi, Geetika Gupta, Dooshaye Moonshiram, Sayantan Paria
Abstract
One-electron oxidation of an Fe<sup>III</sup>–OH complex (<bold>1</bold>) results in the formation of a Fe<sup>III</sup>–OH ligand radical complex (<bold>2</bold>). Its reaction with (C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>C˙ results in the formation of (C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>COH, which is a functional mimic of compound II of cytochrome P450.
Topics & Concepts
Reactivity (psychology)ChemistryLigand (biochemistry)Characterization (materials science)CrystallographyStereochemistryMaterials scienceNanotechnologyBiochemistryAlternative medicinePathologyReceptorMedicineMetal-Catalyzed Oxygenation MechanismsMetal complexes synthesis and propertiesCO2 Reduction Techniques and Catalysts