Self-assembly patterns of non-metalloid silver thiolates: structural, HR-ESI-MS and stability studies
Anastasia V. Chupina, Vadim V. Yanshole, V. S. Sulyaeva, Vasily V. Kokovkin, Pavel A. Abramov⧫, Maxim N. Sokolov⧫
Abstract
The spontaneous formation of nanosized silver/thiolate complexes with torus-like {Ag 20 (S t Bu) 10 } cores has been observed in DMF, DMSO and NMP solutions containing AgNO 3 and AgS t Bu.
Topics & Concepts
Orthorhombic crystal systemCationic polymerizationCrystallographyChemistrySingle crystalNuclear chemistryMaterials sciencePolymer chemistryCrystal structureNanocluster Synthesis and ApplicationsGold and Silver Nanoparticles Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis