Light-gated specific oxidase-like activity of a self-assembled Pt(<scp>ii</scp>) nanozyme for environmental remediation
Rohit Kapila, Bhaskar Sen, Alisha Kamra, Shana Chandran, Subinoy Rana
Abstract
MMLCT state, leading to a specific oxidase-like activity instead of a peroxidase-like activity. The self-assembled nanozyme showed great stability under harsh environmental conditions and exhibited photo-induced specific oxidase-mimetic activity, which was considerably more efficient than the natural enzyme or other specific nanozymes. We demonstrated efficient NanoPtA-induced photocatalytic degradation of various phenolic compounds and azo dyes within 5-10 minutes of light irradiation. Notably, the system operates under sunlight and exhibits reusability over twenty cycles of catalytic reactions. Another fascinating aspect of NanoPtA is the unaltered catalytic performance for more than 75 days, providing a robust enzyme-equivalent for practical sustainable environmental remediation.