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Study of Gallium-Doped Zinc Oxide Thin Films Processed by Atomic Layer Deposition and RF Magnetron Sputtering for Transparent Antenna Applications

Petru Lunca‐Popa, Jean‐Baptiste Chemin, Noureddine Adjeroud, Veronika Kovacova, Sebastjan Glinšek, Nathalie Valle, M. Hachemi, Stéphanie Girod, Olivier Bouton, Jérôme Polesel‐Maris

2023ACS Omega22 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide Gallium-doped zinc oxide (GZO) films were fabricated using RF magnetron sputtering and atomic layer deposition (ALD). The latter ones demonstrate higher electrical conductivities (up to 2700 S cm –1 ) and enhanced charge mobilities (18 cm 2 V –1 s –1 ). The morphological analysis reveals differences mostly due to the very different nature of the deposition processes. The film deposited via ALD shows an increased transmittance in the visible range and a very small one in the infrared range that leads to a figure of merit of 0.009 Ω –1 (10 times higher than for the films deposited via sputtering). A benchmarking is made with an RF sputtered indium-doped tin oxide (ITO) film used conventionally in the industry. Another comparison between ZnO, Al:ZnO (AZO), and Ga:ZnO (GZO) films fabricated by ALD is presented, and the evolution of physical properties with doping is evidenced. Finally, we processed GZO thin films on a glass substrate into patterned transparent patch antennas to demonstrate an application case of short-range communication by means of the Bluetooth Low Energy (BLE) protocol. The GZO transparent antennas’ performances are compared to a reference ITO antenna on a glass substrate and a conventional copper antenna on FR4 PCB. The results highlight the possibility to use the transparent GZO antenna for reliable short-range communication and the achievability of an antenna entirely processed by ALD.

Topics & Concepts

Materials scienceSputter depositionOptoelectronicsAtomic layer depositionSubstrate (aquarium)Thin filmDopingGalliumSputteringPhysical vapor depositionTransmittanceNanotechnologyMetallurgyOceanographyGeologyZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials