Ligand-controlled regiodivergence in cobalt-catalyzed hydrosilylation of isoprene
Sa‐Na Yang, Changhui Liu, Li-Bowen He, Hao Zheng, Chang‐Sheng Kuai, Boshun Wan, Ding‐Wei Ji, Qing‐An Chen
Abstract
An atom-economical, regiodivergent hydrosilylation reaction of isoprene was developed using an Earth-abundant cobalt catalyst through variation of ligands.
Topics & Concepts
HydrosilylationIsopreneChemistryCobaltCatalysisLigand (biochemistry)Organic chemistryPolymer chemistryCopolymerBiochemistryPolymerReceptorOrganometallic Complex Synthesis and CatalysisOrganoboron and organosilicon chemistryAsymmetric Hydrogenation and Catalysis