B–N bond formation through palladium-catalyzed, microwave-assisted cross-coupling of nitrogen compounds with iodo-dodecaborate
Mahmoud K. Al‐Joumhawy, Tarek Marei, Akim V. Shmal’ko, Paula Cendoya, Jair La Borde, Detlef Gabel
Abstract
allows mild and reproducible formation of B-N bonds with aromatic amines, HN-containing heteroaromatics, and amides. The reaction allows general access to amides, reproducible reactions to dodecaborate-substituted anilines, and, for the first time, the substitution of dodecaborate with HN-containing heterocycles.
Topics & Concepts
PalladiumCatalysisNitrogenCoupling (piping)ChemistryMicrowavePolymer chemistryOrganic chemistryMaterials sciencePhysicsComposite materialQuantum mechanicsBoron Compounds in ChemistryPharmacological Effects and Toxicity StudiesOrganoboron and organosilicon chemistry