Pathways to fluorescence <i>via</i> restriction of intramolecular motion in substituted tetraphenylethylenes
Yingchao Li, Adélia J. A. Aquino, Farhan Siddique, Thomas A. Niehaus, Hans Lischka, Dana Nachtigallová
Abstract
groups and a second characterized by a network of hydrogen bonds, have been identified as interesting candidates for creating efficient luminescence properties in solution.
Topics & Concepts
Intramolecular forceConical intersectionSurface modificationTetraphenylethyleneDensity functional theoryChemistryRelaxation (psychology)Steric effectsLuminescenceChemical physicsFluorescenceHydrogen bondPhotochemistryGround stateComputational chemistryBlock (permutation group theory)Surface hoppingPotential energy surfaceMaterials scienceIntersection (aeronautics)HydrogenMoleculeCombinatorial chemistryStokes shiftCarbazoleWork (physics)Photochemistry and Electron Transfer StudiesLuminescence and Fluorescent MaterialsSynthesis and Properties of Aromatic Compounds