New insights into the synthesis of Sillén–Aurivillius oxyhalides: molten salts induce interlayer halogen competing reaction
Yunxiang Zhang, Chenliang Zhou, Shishi Xu, Hazem Abdelsalam, Zhichao Mu, Wei Chen, Zhili Chen, Xiangyu Cheng, Diab Khalafallah, Qinfang Zhang
Abstract
The molten-salt synthesis method offers a special liquid reaction environment that expedites the diffusion of reactive elements and provides the competing reaction of the migrated halogen atoms during the synthesis of Sillén–Aurivillius oxyhalides.
Topics & Concepts
HalogenSillAurivilliusMolten saltInorganic chemistryDiffusionThermiteSalt (chemistry)ChemistryMaterials scienceAluminiumGeologyPhysical chemistryGeochemistryOrganic chemistryThermodynamicsFerroelectricityAlkylDielectricPhysicsOptoelectronicsPolyoxometalates: Synthesis and ApplicationsCatalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen Reduction