Discovering Pseudo-Supertetrahedral Functional Units in Salt-Inclusion Nonlinear Optical Material [Ba<sub>22</sub>(SO<sub>4</sub>)<sub>5</sub>][Zn<sub>14</sub>Ga<sub>18</sub>S<sub>58</sub>]
Jia-Xiang Zhang, Mao‐Yin Ran, A-Yang Wang, Zuju Ma, Xintao Wu, Hua Lin, Qi‐Long Zhu
Abstract
Chalcogenide supertetrahedral functional units play a vital role in both fundamental research and technological applications, but discovering new types of these units remains a significant challenge. This gap is largely due to the difficulty in inducing stable, novel supertetrahedral structures with unique properties. In this work, we successfully synthesize [Ba 22 (SO 4 ) 5 ][Zn 14 Ga 18 S 58 ] ( BZGSO ), the first sulfate-incorporated salt-inclusion chalcogenide, using high-temperature solid-state methods. BZGSO features a unique, noncentrosymmetric FTW-type framework composed of unprecedented pseudosupertetrahedral [Zn 13 Ga 16 S 58 ] functional units. These units are formed by defective [Zn 3 Ga 4 S 16 ] clusters around a [ZnS 6 ] octahedron. Notably, BZGSO exhibits promising characteristics for infrared nonlinear optical applications. The theoretical analysis reveals key structure–property relationships, and a systematic study of X/Zn/Ga/S compounds suggests a trend in structural dimensionality based on [X/(Zn+Ga)] ratios. This work not only advances the understanding of supertetrahedral chemistry but also paves the way for the discovery of materials with potential technological applications.