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A novel approach to the rapid synthesis of high‐entropy carbide nanoparticles

Qinglong Zhao, Jie Mei, Wei Jin, Qi‐Chuan Jiang

2020Journal of the American Ceramic Society22 citationsDOI

Abstract

Abstract A novel strategy for the rapid synthesis of high‐entropy carbide particles is proposed that involves the transformation of multicomponent intermetallic intermediates to multicomponent carbides (high‐entropy carbide precursors). (Ti 0.25 V 0.25 Nb 0.25 Ta 0.25 )C nanoparticles with a uniform solute distribution were successfully synthesized in an Al matrix by heating Al‐Ti‐V‐Nb‐Ta‐C powder mixtures at 1500°C for 10 minutes. The multicomponent aluminide intermediates led to the rapid formation of multicomponent carbides during heating to 1100°C, which transformed into a high‐entropy solid solution during heating to 1500°C. We developed a new rapid approach for the synthesis of high‐entropy ceramic particles.

Topics & Concepts

CarbideMaterials scienceAluminideNanoparticleIntermetallicCeramicEntropy (arrow of time)Chemical engineeringMetallurgyThermodynamicsNanotechnologyPhysicsEngineeringAlloyHigh Entropy Alloys StudiesAdvanced materials and compositesHigh-Temperature Coating Behaviors
A novel approach to the rapid synthesis of high‐entropy carbide nanoparticles | Litcius