Electrochemical Reduction of CO<sub>2</sub> at Coinage Metal Nanodendrites in Aqueous Ethanolamine
M. Nur Hossain, Syed Ahmad, Iranaldo Santos da Silva, Heinz‐Bernhard Kraatz
Abstract
Abstract Electrocatalytic reduction of CO 2 into usable chemicals is a promising path to address climate change and energy challenges. Herein, we demonstrate the synthesis of unique coinage metal (Cu, Ag, and Au) nanodendrites (NDs) via a facile galvanic replacement reaction (GRR), which can be effective electrocatalysts for the reduction of CO 2 in an ethanolamine (EA) solution. Each metal ND surface was directly grown on glassy‐carbon (GC) substrates from a mixture of Zn dust and the respective precursor solution. The electrocatalytic activities of the synthesized ND surfaces were optimized for CO 2 reduction in EA solution by varying their composition. It was determined that a 0.05 mol fraction of EA exhibited the highest catalytic activity for all metal NDs. Linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS) techniques showed that metal‐ND electrodes possessed higher current densities, lower onset potentials and lower charge‐transfer resistances for CO 2 reduction than their smooth polycrystalline electrode counterparts, indicating improved CO 2 reduction catalytic activity. It was determined, using FTIR and NMR spectroscopy, that formate was produced as a result of the CO 2 reduction.