Textured Potassium Sodium Niobate Lead-Free Ceramics with High <i>d</i><sub>33</sub> and <i>Q</i><sub>m</sub> for Meeting High-Power Applications
Dong Liu, Lifeng Zhu, Ting Tang, Jingrui Li, Long Wang, Yixuan Liu, Junjie Hao, Shidong Wang, Ke Wang
Abstract
Potassium sodium niobate (KNN) lead-free piezoceramics have garnered significant attention for their environmentally friendly attributes, desired piezoelectric activity ( d 33 ), and high Curie temperature ( T c ). However, the limited applicability of most KNN systems in high-power apparatus, including ultrasonic motors, transformers, and resonators, persists due to the inherent low mechanical quality factor ( Q m ). Herein, we proposed an innovative strategy for achieving high Q m accompanied by desirable d 33 via synergistic chemical doping and texturing in KNN piezoceramics. Comprehensive electrical measurements along with quantitative structural characterization at multilength scales reveal that the excellent electromechanical properties ( k p = 0.58, d 33 ∼ 134 pC·N -1, Q m = 582, and T c ∼ 415 °C) originate from the high <001> texturing degree, nanodomain, as well as acceptor hardening. Our findings provide an insight and guidance for achieving high-power performance in lead-free KNN-based piezoceramics, which were expected to be used in advanced transducer technology.