Ground tire rubber/polyamide 6 thermoplastic elastomers produced by dry blending and compression molding
Roberto Carlos Vázquez Fletes, Erick Omar Cisneros‐López, Pedro Ortega‐Gudiño, E. Mendizábal, Rubén González‐Núñez, Denis Rodrigue
Abstract
This study investigates the addition of ground tire rubber (GTR) into virgin polyamide 6 (PA6) to produce thermoplastic elastomer (TPE) blends. In particular, a wide range of GTR concentration (0–100% wt.) was possible by using a simple dry blending technique of the materials in a powder form followed by compression molding. The molded samples were characterized in terms of morphological (scanning electron microscopy), physical (density and hardness) and mechanical (tension, flexion and impact) properties. The results showed a decrease in tensile and flexural moduli and strengths with GTR due to its elastomeric nature. However, significant increases were observed on the tensile elongation at break (up to 167%) and impact strength (up to 131%) compared to the neat PA6 matrix. Based on the results obtained, an optimum GTR content around 75% wt. was observed which represents a balance between high recycled rubber content and a sufficient amount of matrix to recover all the particles. These results represent a first step showing that a simple processing method can be used to produce low cost PA6/GTR compounds with a wide range of physical and mechanical properties.