Concurrent base and silver(<scp>i</scp>) catalysis pulsed by fuel acid
Isa Valiyev, Amit Ghosh, Indrajit Paul, Michael Schmittel
Abstract
Treatment of a crown-ether receptor and a silver(I)-loaded cyclam derivative (NetState-I) with a fuel acid reversibly afforded the protonated cyclam and the silver(I)-loaded crown ether (NetState-II). While NetState-I was catalytically OFF, a base-catalysed Michael addition and a silver(I)-catalysed oxime cyclisation reaction was pulsed under dissipative conditions in NetState-II.
Topics & Concepts
CyclamChemistryCrown etherProtonationBase (topology)CatalysisDerivative (finance)Polymer chemistryEtherMedicinal chemistryOrganic chemistryCombinatorial chemistryMetalIonFinancial economicsMathematical analysisEconomicsMathematicsSupramolecular Chemistry and ComplexesSynthetic Organic Chemistry MethodsChemical Synthesis and Analysis