Green synthesis of sulfur-containing polymers by carbon disulfide-based spontaneous multicomponent polymerization
Chen Xu, Anjun Qin, Ben Zhong Tang
Abstract
A spontaneous multi-component polymerization of activated internal alkynes, amines, and CS 2 was established. Similar to the ancient “tenon and mortise” structure, CS 2 acts as a “wedge” to link the other two monomers to form sulfur-containing polymers.
Topics & Concepts
PolymerizationSulfurMonomerCarbon disulfidePolymerChemistryPolymer chemistryDisulfide bondOrganic chemistryBiochemistryCarbon dioxide utilization in catalysisSulfur-Based Synthesis TechniquesSynthetic Organic Chemistry Methods