Ligand-controlled cobalt-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes
Pei Zhao, Jiaxin Huang, Jie Li, Kezhuo Zhang, Wen Yang, Wanxiang Zhao
Abstract
The Co-catalyzed remote hydroboration and alkene isomerization of allylic siloxanes were realized by a ligand-controlled strategy. The remote hydroboration with dcype provided borylethers, while xantphos favored the formation of silyl enol ethers.
Topics & Concepts
HydroborationIsomerizationAlkeneChemistryAllylic rearrangementXantphosLigand (biochemistry)SilylationCatalysisEnolCobaltOrganic chemistryPhotochemistryPalladiumBiochemistryReceptorOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization Methods