Silver nanoparticle-decorated titanium dioxide nanowire systems <i>via</i> bioinspired poly(<scp>l</scp>-DOPA) thin film as a surface-enhanced Raman spectroscopy (SERS) platform, and photocatalyst
Hayrunnisa Mazlumoğlu, Mehmet Yılmaz
Abstract
Silver nanostructure decorated-titanium dioxide (TiO2) nanocomposite systems with their unique characteristics provide extraordinary performance in various applications including surface-enhanced Raman spectroscopy (SERS), and photocatalysis. Despite the recent progress, novel, simple, effective, low-cost, reducing and stabilizing agent-free, and easy-to-tune approaches are heavily demanded for the preparation of these nanocomposites. In this context, we propose the fabrication of silver nanostructure decorated TiO2 nanowires (TiO2 NWs) through a thin interphase layer of the polymer of 3,4-dihydroxyphenyl-l-alanine (PLDOPA). In the first step, TiO2 NWs were synthesized through the hydrothermal method and then a conformal thin film of PLDOPA was deposited onto the TiO2 NWs (TiO2@PLDOPA) by oxidative polymerization of l-DOPA. Having various functional groups including catechol and amine, the PLDOPA thin-film reduced the silver ions onto the TiO2 NWs and stabilized the resultant nanocomposites without the employment of any surfactant, reducing agent, and seed material. By simply tuning the amount of silver ions, we could manipulate the size, morphology, and interparticle distance of silver nanostructures decorated onto the TiO2@PLDOPA colloidal composite system (TiO2@PLDOPA@Ag NP). The TiO2@PLDOPA@Ag nanocomposite systems provided unique properties as an ideal SERS platform and photocatalyst. The optimized TiO2@PLDOPA@Ag nanosystem demonstrated a high SERS activity, reproducibility, and self-cleaning property with an enhancement factor of 5.1 × 105. As a photocatalyst, the TiO2@PLDOPA@Ag NP systems provided remarkable performance under visible light irradiation in the catalytic degradation of methylene blue.