Chiral Zero‐Dimensional Hybrid Antimony Chloride with Circularly Polarized Luminescence and Solvent‐Induced Property Regulation
Min Tao, Rui Cao, Shuo Sun, H. Li, Yin Xiao
Abstract
Abstract In this study, we synthesized two pairs of enantiomeric Sb 3+ ‐based 0D chiral hybrid metal halides (HMHs), ( R / S ‐3AP) 4 SbCl 11 ⋅DMF and ( R / S ‐3AP) 4 SbCl 11 ⋅ACN, which exhibit efficient circularly polarized luminescence (CPL) emissions with distinct optical properties influenced by the solvent environment. ( R / S ‐3AP) 4 SbCl 11 ⋅DMF displays bright orange luminescence with a photoluminescence quantum yield (PLQY) of 57.1 %, while ( R / S ‐3AP) 4 SbCl 11 ⋅ACN emits red luminescence with a PLQY of 17.4 %. Notably, ( R / S ‐3AP) 4 SbCl 11 ⋅ACN achieves a maximum dissymmetry factor (| g lum |) of 2.27×10 −3 , attributed to strong hydrogen bonding between organic and inorganic components. Reversible transformations between these two phases via solvent vapor stimulation enable dynamic photoluminescence (PL) switching, highlighting their application in anti‐counterfeiting technology. Furthermore, circularly polarized light‐emitting devices (CPL‐emitting devices) based on these materials were fabricated, achieving a maximum | g lum | of 2.01×10 −3 . These findings underscore the potential of these chiral HMHs for advanced applications in chiral optoelectronics, anti‐counterfeiting, and CPL‐emitting devices.