1,2,3-Triazol-5-ylidene- <i>vs.</i> 1,2,3-triazole-based tricarbonylrhenium(<scp>i</scp>) complexes: influence of a mesoionic carbene ligand on the electronic and biological properties
Corinne Vanucci‐Bacqué, Mariusz Wolff, Béatrice Delavaux‐Nicot, Abanoub Mosaad Abdallah, Sonia Mallet‐Ladeira, Charles-Louis Serpentini, Florence Bedos‐Belval, Kar Wai Fong, Xiao Ying Ng, May Lee Low, Éric Benoist, Suzanne Fery‐Forgues
Abstract
Two series of tricarbonylrhenium( i ) complexes were thoroughly compared. One 1,2,3-triazole-based complex displayed astounding photoluminescence properties, while one triazolylidene-based complex showed promising antibacterial activity.
Topics & Concepts
MesoionicCarbeneLigand (biochemistry)ChemistryTriazole1,2,4-TriazoleCombinatorial chemistryPhotoluminescenceStereochemistryMedicinal chemistryOrganic chemistryMaterials scienceReceptorBiochemistryCatalysisOptoelectronicsN-Heterocyclic Carbenes in Organic and Inorganic ChemistryClick Chemistry and ApplicationsCatalytic Cross-Coupling Reactions