Reactive SPS for sol–gel alumina samples: Structure, sintering behavior, and mechanical properties
Pedro Rivero-Antúnez, Rafael Cano‐Crespo, F. Sánchez‐Bajo, A. Domı́nguez-Rodrı́guez, Víctor Morales‐Flórez
Abstract
This work presents a fast and direct controlled routine for the fabrication of fully dense alumina based on the reactive spark plasma sintering (reactive-SPS) of boehmite (γ-AlOOH) nano-powders obtained by the sol–gel technique. The evolution of the transition aluminas during sintering has been studied. Some boehmite powders were seeded with α-Al2O3 particles prior to the gelation. Boehmite seeded powders exhibited a direct transition to α-Al2O3 at 1070 °C, enhancing the transformation kinetics and lowering the required temperature by more than 100 °C. For comparison, other samples were prepared by previously annealing the seeded and unseeded boehmite powders. Thus, α-Al2O3 powders were obtained and were sintered by standard-SPS. A detailed structural and mechanical characterization is presented, comparing the hardness and indentation fracture resistance for different grain sizes and porosities. Both the reactive-SPSed samples and the standard-SPSed samples showed a high hardness (18–20 GPa), whereas the reactive-SPSed samples exhibited a lower indentation fracture resistance due to a large grain size (∼10 μm). Improvements of this procedure for obtaining smaller grain size are discussed. In summary, the presented technique brings a revolutionary fast method for the fabrication of fully dense alumina, as this process reduces the time and temperature required for alumina densification.