Optical resolution of pseudo-<i>para</i>-disubstituted [2.2]paracyclophane: a chiral building block for optically active helicene-stacked molecules emitting circularly polarized luminescence
Asuka Yanagawa, Motoki Tsuchiya, Ryo Inoue, Yasuhiro Morisaki
Abstract
Optical resolution of pseudo- para -disubstituted [2.2]paracyclophane was achieved by the diastereomer method. Enantiopure optically active molecules emitting circularly polarized luminescence were synthesized.
Topics & Concepts
Enantiopure drugLuminescenceOptically activeHeliceneMaterials scienceMoleculeDiastereomerResolution (logic)Circular polarizationOptoelectronicsPhotochemistryOpticsStereochemistryOrganic chemistryChemistryPhysicsEnantioselective synthesisCatalysisArtificial intelligenceMicrostripComputer scienceSynthesis and Properties of Aromatic CompoundsPhotoreceptor and optogenetics researchPhotochromic and Fluorescence Chemistry