Tuning oxygen-containing functional groups of graphene for supercapacitors with high stability
Shiqi Lin, Jie Tang, Kun Zhang, You‐Hu Chen, Runsheng Gao, Hang Yin, Lu‐Chang Qin
Abstract
structure in the rGO sheet was restored and the obtained rGO had good crystallinity accompanied by removal of the oxygenic functional groups. The analysis of the content of the different functional groups also suggested that the reduction rate of the oxygenic functional group was C-O > C[double bond, length as m-dash]O > O-C[double bond, length as m-dash]O. The supercapacitive performance of rGO showed that the oxygenic functional groups contributed to some pseudocapacitance and resulted in a larger specific capacitance. At the same time, however, it is also accompanied by poorer rate performance and durability, which will be improved by removing the oxygenic functional groups by extending the reduction time. With an optimized reaction condition of a reduction time of 24 h, the obtained rGO exhibited excellent stability in floating tests at 3.0 V and 45 °C for 60 days. These findings pave the way for the development of high quality graphene materials for cost-effective and practical graphene supercapacitors.