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Functionalization of 1,2,3-Triazole to Pyrimidine, Pyridine, Pyrazole, and Isoxazole Fluorophores with Antimicrobial Activity

Atef M. Abdel Hamid, Hassan A. El‐Sayed, Samar M. Mohammed, Ahmed H. Moustafa, Hesham A. Morsy

2020Russian Journal of General Chemistry17 citationsDOI

Abstract

Abstract The multi-component reaction of diacetyl triazole derivative with ethyl cyanoacetate and various aromatic aldehydes according to the conventional and solvent free methods leads to the corresponding 2-oxonicotinonitriles. A number of chalcones has been obtained via condensation of diacetyl triazole derivative with a variety of aromatic aldehydes. Heterocyclization of dichalcones with thiourea, hydroxyl amine, 3-aminocrotononitrile and hydrazine hydrate leads to a series of functionalized triazoles. Fluorescent properties of some products have been studied and characterized by λem.max 463–499 nm. A series of newly synthesized compounds demonstrate high antimicrobial activity against the tested microorganisms.

Topics & Concepts

ChemistryPyrazoleIsoxazoleThioureaAntimicrobialTriazolePyrimidineImidazolePyridineHydrazine (antidepressant)Organic chemistryCombinatorial chemistryHydrate1,2,4-TriazoleStereochemistryChromatographySynthesis and biological activityMulticomponent Synthesis of HeterocyclesSynthesis and Characterization of Heterocyclic Compounds
Functionalization of 1,2,3-Triazole to Pyrimidine, Pyridine, Pyrazole, and Isoxazole Fluorophores with Antimicrobial Activity | Litcius