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A comparative study on the structural features of humic acids extracted from lignites using comprehensive spectral analyses

Yuanqin Zhang, Yanhong Li, Liping Chang, Changyu Zi, Guangbing Liang, Dengfeng Zhang, Yi Su

2020RSC Advances31 citationsDOIOpen Access PDF

Abstract

C NMR, which is rarely used to analyze the structures of HAs using fitting peaks, and FT-IR spectrum analyses indicated that both the aromaticity and the oxygen-containing group contents of ZLHA are higher than those of MLHA, and the HAs' aromaticity could be confirmed by the results of the X-ray diffraction patterns. Additionally, the main existing forms of the elements in the HAs were obtained from X-ray photoelectron spectrum analyses, which are not commonly used for HA analyses. In this work, the utilization of comprehensive spectral analyses was an effective method to study the structural features of ZLHA and MLHA and it could provide a basic reference for the applications of ZLHA and MLHA.

Topics & Concepts

AromaticityMagic angle spinningChemistryCarbon-13 NMRMoleculeNuclear magnetic resonance spectroscopyOrganic chemistryPlant Growth Enhancement TechniquesCoal and Its By-productsHeavy metals in environment