Purification mechanism of microcrystalline graphite and lithium storage properties of purified graphite
Sen Yang, Shuaiqing Zhang, Wei Dong, Yingkai Xia
Abstract
Abstract In order to improve the application value of natural microcrystalline graphite with carbon content of 49.5%, high-purity microcrystalline graphite was prepared by emulsifying kerosene flotation firstly, and then purifying hydrofluoric acid and hexafluorosilicic acid. Then the purified microcrystalline graphite was prepared for the lithium-ion battery anode material, its microstruture and electrochemical properties were analyzed, the purification mechanism and lithium storage mechanism were discussed. The research results show that carbon content of microcrystalline graphite after emulsified kerosene flotation and mixed acid purification are 93.5% and 99.0% respectively. After pickling, high-purity microcrystalline graphite shows the largest layer spacing, which is 0.351 5 nm and is 0.001 4 nm higher than that of natural microcrystalline graphite. Size disparity of acid washing sample is larger, layered structure is more obvious, cycle performance and magnification performance are better than those of floation sample. The pickled sample has the highest initial reversible specific capacity of 477.4 mAh/g, and the first Coulomb efficiency is 61.3%. Charge transfer impedance, interface impedance and SEI membrane impedance, and lithium ion diffusion impedance in electrode material are significantly lower than those of microcrystalline graphite after flotation.