Structural and ethylene oligomerization studies of chelating (imino)phenol Fe(<scp>ii</scp>), Co(<scp>ii</scp>) and Ni(<scp>ii</scp>) complexes: an experimental and theoretical approach
Makhosonke Ngcobo, Holliness Nose, Arumugam Jayamani, Stephen O. Ojwach
Abstract
Experimental and theoretical data indicate that the stability and metal charge of N^O Fe( ii ), Co( ii ) and Ni( ii ) complexes control their catalytic activities in ethylene oligomerization reactions.
Topics & Concepts
ChemistryEthyleneChelationCatalysisPhenolNickelMetalMedicinal chemistryStereochemistryOrganic chemistryOrganometallic Complex Synthesis and CatalysisMagnetism in coordination complexesAsymmetric Hydrogenation and Catalysis