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Reverse-Bias and Temperature Behaviors of Perovskite Solar Cells at Extended Voltage Range

Leyla Najafi, Sebastiano Bellani, Luca Gabatel, Marilena Isabella Zappia, Aldo Di Carlo, Francesco Bonaccorso

2022ACS Applied Energy Materials37 citationsDOIOpen Access PDF

Abstract

Perovskite solar cells have reached certified power conversion efficiency over 25%, enabling the realization of efficient large-area modules and even solar farms. It is therefore essential to deal with technical aspects, including the reverse-bias operation and hot-spot effects, which are crucial for the practical implementation of any photovoltaic technology. Here, we analyze the reverse bias (from 2.5 to 30 V) and temperature behavior of mesoscopic cells through infrared thermal imaging coupled with current density measurements. We show that the occurrence of local heating (hot-spots) and arc faults, caused by local shunts, must be considered during cell and module designing.

Topics & Concepts

Mesoscopic physicsPhotovoltaic systemPerovskite (structure)Materials scienceRealization (probability)BiasingRange (aeronautics)VoltageReverse biasOptoelectronicsEnergy conversion efficiencyEngineering physicsSolar cellElectrical engineeringPhysicsCondensed matter physicsEngineeringComposite materialChemical engineeringMathematicsStatisticsDiodePerovskite Materials and ApplicationsThin-Film Transistor TechnologiesChalcogenide Semiconductor Thin Films
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