Litcius/Paper detail

Asymmetric seven-/eight-step spin-crossover in a three-dimensional Hofmann-type metal–organic framework

Yuanyuan Peng, Si‐Guo Wu, Yan‐Cong Chen, Wei Liu, Guo‐Zhang Huang, Zhao‐Ping Ni, Ming‐Liang Tong

2020Inorganic Chemistry Frontiers53 citationsDOI

Abstract

An unprecedented hysteretic seven-/eight-step spin-crossover behavior is revealed. Most importantly, a molecular alloy based on a Hofmann-type framework is used as a strategy to explore multi-step spin-crossover materials for the first time.

Topics & Concepts

Spin crossoverCrossoverSpin (aerodynamics)Type (biology)Materials scienceAlloyMetalCondensed matter physicsPhysicsMetallurgyComputer scienceThermodynamicsEcologyBiologyArtificial intelligenceMagnetism in coordination complexesOrganic and Molecular Conductors ResearchLanthanide and Transition Metal Complexes