Zn<sub>0.52</sub>V<sub>2</sub>O<sub>5−<i>a</i></sub>⋅1.8 H<sub>2</sub>O Cathode Stabilized by In Situ Phase Transformation for Aqueous Zinc‐Ion Batteries with Ultra‐Long Cyclability
Wenhao Liang, Dewei Rao, Tao Chen, Rongfeng Tang, Jun Li, Huile Jin
Abstract
Abstract Developing cathode materials integrating good rate performance and sufficient cycle life is the key to commercialization of aqueous zinc‐ion batteries. The hyperstable Zn 0.52 V 2 O 5− a ⋅1.8 H 2 O (ZVOH) cathode with excellent rate performance has been successfully developed via an in situ self‐transformation from zinc‐rich Zn 3 V 3 O 8 (ZVO) in this study. Different from the common synthetic method of additional Zn 2+ pre‐insertion, ZVOH is obtained from the insertion of structural H 2 O and the removal of excess Zn 2+ in ZVO, ensuring the lattice structure of ZVOH remains relatively intact during the phase transition and rendering good structural stabilities. The ZVOH delivers a reversible capacity of 286.2 mAh g −1 at 0.2 A g −1 and of 161.5 mAh g −1 at 20 A g −1 over 18 000 cycles with a retention of 95.4 %, demonstrating excellent rate performance and cyclic stability. We also provide new insights on the structural self‐optimization of Zn x (CF 3 SO 3 ) y (OH) 2 x − y ⋅ n H 2 O byproducts and the effect on the mobility of Zn 2+ by theoretical calculations and experimental evidence.