A window-space-directed assembly strategy for the construction of supertetrahedron-based zeolitic mesoporous metal–organic frameworks with ultramicroporous apertures for selective gas adsorption
Lei Zhang, Fangfang Li, Jianjun You, Nengbin Hua, Qianting Wang, Junhui Si, Wenzhe Chen, Wenjing Wang, Xiao‐Yuan Wu, Wenbin Yang, Daqiang Yuan, Can‐Zhong Lu, Yanrong Liu, Abdullah M. Al‐Enizi, Ayman Nafady, Shengqian Ma
Abstract
A series of supertetrahedron (ST)-based sodalite (<bold>sod</bold>)-topology zeolitic MOFs specimens ST-<bold>sod</bold>-MOFs featuring ultramicroporous square windows and a mesoporous sodcage have been synthesized <italic>via</italic> a window-space-directed assembly approach.
Topics & Concepts
Mesoporous materialMetal-organic frameworkAdsorptionWindow (computing)Materials scienceZeoliteNanotechnologyChemical engineeringCharacterisation of pore space in soilChemistryPorosityComputer scienceOrganic chemistryCatalysisEngineeringComposite materialOperating systemMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCatalytic Processes in Materials Science