Deciphering charge transfer dynamics of a lead halide perovskite–nickel( <scp>ii</scp> ) complex for visible light photoredox C–N coupling
Vishesh Kumar, Sunil Kumar Patel, Ved Vyas, Deepak Kumar, E. Siva Subramaniam Iyer, Arindam Indra
Abstract
The introduction of Ni(dmgH) 2 as a cocatalyst with CsPbBr 3 quantum dots facilitates the activation of molecular oxygen to superoxide radical, initiating radical catalyzed C–N coupling between aldehyde and amine to form amide.
Topics & Concepts
HalideAldehydeChemistryPhotochemistryNickelAmidePhotoredox catalysisAmine gas treatingPerovskite (structure)CatalysisVisible spectrumInorganic chemistryMaterials scienceCrystallographyOrganic chemistryPhotocatalysisOptoelectronicsPerovskite Materials and ApplicationsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques