Extensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Study
Ranjeesh Thenarukandiyil, Eno Paenurk, Anthony Wong, Natalia Fridman, Amir Karton, Raanan Carmieli, Gabriel Ménard, Renana Gershoni‐Poranne, Graham de Ruiter
Abstract
Fe Mössbauer and EPR spectroscopy) and computational studies were employed to elucidate the electronic structure of the isolated complexes, which are further discussed in this report.
Topics & Concepts
ChemistryRedoxDiimineElectron transferElectron paramagnetic resonanceMetalLigand (biochemistry)Mössbauer spectroscopyBipyridineCrystallographyPhotochemistryNon-innocent ligandCatalysisInorganic chemistryCrystal structureOrganic chemistryNuclear magnetic resonanceReceptorPhysicsBiochemistryMetal-Catalyzed Oxygenation MechanismsCO2 Reduction Techniques and CatalystsMetal complexes synthesis and properties