<i>S</i> = 3 Ground State for a Tetranuclear Mn<sup>IV</sup><sub>4</sub>O<sub>4</sub> Complex Mimicking the S<sub>3</sub> State of the Oxygen-Evolving Complex
Heui Beom Lee, David A. Marchiori, Ruchira Chatterjee, Paul H. Oyala, Junko Yano, R. David Britt, Theodor Agapie
Abstract
complex described here. This sets a synthetic precedent for the observed low-spin to high-spin conversion in the OEC.
Topics & Concepts
ChemistryElectron paramagnetic resonanceGround stateOxygen-evolving complexCrystallographyHyperfine structureSpin statesOxidation stateTrimerPhotosystem IIAtomic physicsDimerNuclear magnetic resonanceInorganic chemistryPhysicsCatalysisOrganic chemistryPhotosynthesisBiochemistryPhotosynthetic Processes and MechanismsPhotoreceptor and optogenetics researchSpectroscopy and Quantum Chemical Studies