Assembly of dysprosium(<scp>iii</scp>) cubanes in a metal–organic framework with an ecu topology and slow magnetic relaxation
Dong Shao, Yi Wan, Jiong Yang, Zhijun Ruan, Junlun Zhu, Le Shi
Abstract
A rare dysprosium( iii ) metal–organic framework constructed using dysprosium( iii ) cubanes as secondary building units has been reported to exhibit field-supported single-molecule magnet (SMM) behavior and an unprecedented ecu topology.
Topics & Concepts
DysprosiumMagnetic relaxationRelaxation (psychology)CubaneChemistryTopology (electrical circuits)Metal-organic frameworkCrystallographyMetalMagnetic fieldChemical physicsInorganic chemistryPhysical chemistryPhysicsOrganic chemistryCrystal structureCombinatoricsQuantum mechanicsNeuroscienceMathematicsBiologyAdsorptionMagnetizationMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications