Alkyne insertion into Cu–Al bonds and selective functionalization to form copper acyl compounds
Caitilín McManus, Agamemnon E. Crumpton, Simon Aldridge
Abstract
systems) and regioselective (to Cu-C bonds), leading to the formation of the first structurally characterized examples of copper acyl compounds - aided by the cooperative reactivity of the proximal aluminium centre.
Topics & Concepts
AlkyneCopperChemistryRegioselectivitySurface modificationReactivity (psychology)DerivatizationStereoselectivityCombinatorial chemistryStereochemistryOrganic chemistryCatalysisPhysical chemistryMedicineAlternative medicineHigh-performance liquid chromatographyPathologyOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsCoordination Chemistry and Organometallics