Synthesis and structural characterization of stable coinage metal (Cu, Ag, Au) cyclopentadienyl complexes
Robin Sievers, Marc Reimann, Nico G. Kub, Susanne M. Rupf, Martin Kaupp, Moritz Malischewski
Abstract
We report the first complete series of structurally characterized cyclopentadienyl complexes of coinage metals. Their unusually high stability is due to the high oxidative stability of the perfluorinated Cp* ligand [C 5 (CF 3 ) 5 ] − .
Topics & Concepts
Cyclopentadienyl complexMetalChemistryCharacterization (materials science)Ligand (biochemistry)CopperCrystallographyPolymer chemistryStereochemistryMaterials scienceNanotechnologyOrganic chemistryReceptorCatalysisBiochemistryOrganometallic Complex Synthesis and CatalysisFluorine in Organic ChemistryCyclopropane Reaction Mechanisms