Vanillin-derived α,ω-diene monomer for thermosets preparation <i>via</i> thiol–ene click polymerization
Zijun Gao, Yang You, Qin Chen, Michael North, Haibo Xie
Abstract
Novel vanillin-derived α,ω-diene monomer was synthesized via Williamson and Tishchenko reaction, which was readily polymerized with thiols to obtain thiol-ene networks with tunable material properties and satisfactroy degradability under mild alkaline conditions.
Topics & Concepts
MonomerEne reactionVanillinPolymerizationDieneThiolChemistryPolymer chemistryClick chemistryThermosetting polymerOrganic chemistryPolymerNatural rubberPhotopolymerization techniques and applicationsAdvanced Polymer Synthesis and CharacterizationCarbon dioxide utilization in catalysis