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Nitrogen plasma passivated niobium resonators for superconducting quantum circuits

Kaiwen Zheng, Daria Kowsari, N. J. Thobaben, Xinyi Du, Xingrui Song, Sheng Ran, Erik Henriksen, David Wisbey, Kater Murch

2022Applied Physics Letters31 citationsDOIOpen Access PDF

Abstract

Microwave loss in niobium metallic structures used for superconducting quantum circuits is limited by a native surface oxide layer formed over a timescale of minutes when exposed to an ambient environment. In this work, we show that nitrogen plasma treatment forms a niobium nitride layer at the metal–air interface, which prevents such oxidation. X-ray photoelectron spectroscopy confirms the doping of nitrogen more than 5 nm into the surface and a suppressed oxygen presence. This passivation remains stable after aging for 15 days in an ambient environment. Cryogenic microwave characterization shows an average filling-factor-adjusted two-level-system loss tangent FδTLS of (2.9±0.5)·10−7 for resonators with a 3 μm center strip and (1.0±0.3)·10−7 for a 20 μm center strip, exceeding the performance of unpassivated samples by a factor of four.

Topics & Concepts

NiobiumPassivationSuperconductivityX-ray photoelectron spectroscopyMaterials scienceNitrogenNitrideDissipation factorNiobium nitrideCondensed matter physicsAnalytical Chemistry (journal)MetalCenter (category theory)Layer (electronics)ChemistryPhysicsCrystallographyNanotechnologyOptoelectronicsNuclear magnetic resonanceMetallurgyChromatographyOrganic chemistryDielectricQuantum and electron transport phenomenaPhysics of Superconductivity and MagnetismSemiconductor Quantum Structures and Devices