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Synthesis of new quinolizinium-based fluorescent compounds and studies on their applications in photocatalysis

Wai-Ming Yip, Qiong Yu, Ajcharapan Tantipanjaporn, Wing-Cheung Chan, Jie‐Ren Deng, Ben C.B. Ko, Man‐Kin Wong

2021Organic & Biomolecular Chemistry24 citationsDOI

Abstract

. A library of new quinolizinium compounds was synthesized from quinolines and internal alkyne substrates in up to 65% isolated yields. Systematic studies of their photophysical properties were conducted. The quinoliziniums have been used in three visible-light-induced photocatalysis reactions with good yields.

Topics & Concepts

ChemistryCationic polymerizationPhotocatalysisFluorescenceCombinatorial chemistryAlkyneIonic bondingIntercalation (chemistry)PhotochemistryOrganic chemistryCatalysisIonQuantum mechanicsPhysicsRadical Photochemical ReactionsLuminescence and Fluorescent MaterialsCatalytic C–H Functionalization Methods