Catalytic regio- and stereoselective silicon–carbon bond formations on unsymmetric <i>gem</i>-difluorocyclopropenes by capture of silyl metal species
Hao Xu, Xiao‐Jun Fang, Wei‐Sheng Huang, Zheng Xu, Li Li, Fei Ye, Jian Cao, Li‐Wen Xu
Abstract
A highly regioselective silylation of unsymmetric gem -difluorocyclopropenes was achieved by the capture of in-situ formed silyl metal intermediates, which gave structurally diverse silyldifluorocyclopropanes with good yields and stereoselectivity.
Topics & Concepts
SilylationStereoselectivityChemistryRegioselectivityMetalCatalysisSiliconCarbon fibersStereochemistryMedicinal chemistryOrganic chemistryMaterials scienceComposite numberComposite materialCyclopropane Reaction MechanismsFluorine in Organic ChemistryCatalytic Cross-Coupling Reactions