CsAB<sub>8</sub>O<sub>12</sub>F<sub>2</sub>·CsI (A = K<sup>+</sup>, NH<sub>4</sub><sup>+</sup>): design of two fluorooxoborates with benign layered structures<i>via</i>a salt-inclusion strategy
Yuchen Yan, Jiahao Jiao, Chenchen Tu, Min Zhang, Zhihua Yang, Shilie Pan
Abstract
A salt-inclusion strategy was adopted to construct two novel fluorooxoborates CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ). Therein, CsKB 8 O 12 F 2 ·CsI shows moderate SHG response (0.6 × KDP at 1064 nm) and short phase-matching (PM) SHG wavelength (270 nm).
Topics & Concepts
Materials sciencePhase matchingWavelengthAnalytical Chemistry (journal)CrystallographyOpticsPhysicsOptoelectronicsChemistryLaserChromatographyCrystal Structures and PropertiesX-ray Diffraction in CrystallographyInorganic Fluorides and Related Compounds