Recent advances in iridium-catalyzed enantioselective allylic substitution using phosphoramidite-alkene ligands
Takahiro Sawano, Ryo Takeuchi
Abstract
This minireview describes the recent progress of iridium-catalyzed enantioselective allylic substitution using phosphoramidite-alkene ligands realizing highly enantioselective carbon–carbon and carbon–heteroatom bond formation.
Topics & Concepts
Enantioselective synthesisPhosphoramiditeAlkeneAllylic rearrangementIridiumHeteroatomChemistryCatalysisCombinatorial chemistryOrganic chemistryAlkylDNAOligonucleotideBiochemistryAsymmetric Synthesis and CatalysisAsymmetric Hydrogenation and CatalysisAdvanced Synthetic Organic Chemistry