Evidence for Suzuki–Miyaura cross-couplings catalyzed by ligated Pd <sub>3</sub> -clusters: from cradle to grave
Neda Jeddi, Neil W. J. Scott, Theo F. N. Tanner, Simon K. Beaumont, Ian J. S. Fairlamb
Abstract
Pd n clusters offer unique selectivity and exploitable reactivity in catalysis. Tethering Pd 3 clusters to a resin unlocks compelling new insight into the speciation of Pd during catalytic turnover for Suzuki–Miyaura cross-couplings.
Topics & Concepts
CatalysisChemistryCombinatorial chemistryComputer scienceOrganic chemistryNanocluster Synthesis and ApplicationsCatalytic Cross-Coupling ReactionsQuantum Dots Synthesis And Properties