Efficient suppression of the chain transfer reaction in ethylene coordination polymerization with dibenzosuberyl substituents
Zhou Lu, Yudan Liao, Weigang Fan, Shengyu Dai
Abstract
Catalysts with dibenzosuberyl substituents possess a superior ability to suppress chain transfer in ethylene (co)polymerization, producing high molecular weight polyethylenes and functionalized polyethylenes (ethylene-MA copolymers).
Topics & Concepts
Chain transferChemistryEthylenePolymerizationPolymer chemistryTransfer (computing)PhotochemistryCombinatorial chemistryOrganic chemistryCatalysisRadical polymerizationComputer sciencePolymerParallel computingOrganometallic Complex Synthesis and CatalysisSynthetic Organic Chemistry MethodsCarbon dioxide utilization in catalysis