Two-dimensional infrared spectroscopy as a tool to reveal the vibrational and molecular structure of [FeFe] hydrogenases
Cornelius C. M. Bernitzky, Yvonne Rippers, D.J. Le Poire, Mathesh Vaithiyanathan, Solomon L. D. Wrathall, Barbara Procacci, Igor V. Sazanovich, Gregory M. Greetham, Patricia Rodríguez‐Maciá, Neil T. Hunt, James A. Birrell, Marius Horch
Abstract
state, in solution and at ambient temperature. In conclusion, the introduced combination of experimental and computational 2D-IR spectroscopy represents a powerful approach for studying [FeFe] hydrogenases and other complex organometallic targets.
Topics & Concepts
HydrogenaseInfraredInfrared spectroscopyMolecular spectroscopySpectroscopyChemistryMoleculeCrystallographyPhotochemistryMaterials scienceChemical physicsPhysicsOpticsOrganic chemistryHydrogenQuantum mechanicsMetalloenzymes and iron-sulfur proteinsElectrocatalysts for Energy ConversionAmmonia Synthesis and Nitrogen Reduction