Reactivities of hydrated electrons with organic compounds in aqueous-phase advanced reduction processes
Rose Daily, Daisuke Minakata
Abstract
Novel linear free energy relationships were determined between experimentally measured rate constants of solvated electrons and theoretically calculated one electron reduction potential for the elucidation of reductive reaction mechanisms.
Topics & Concepts
Solvated electronElectronReduction (mathematics)Aqueous solutionOne-electron reductionChemistryReaction rate constantPhase (matter)Chemical physicsComputational chemistryPhysical chemistryInorganic chemistryKineticsOrganic chemistryRadiolysisElectrochemistryPhysicsQuantum mechanicsElectrodeGeometryMathematicsElectrochemical Analysis and ApplicationsSpectroscopy and Quantum Chemical StudiesElectrocatalysts for Energy Conversion